Opening and Feeding the Hive - Step 1
Smoke the Hive
Smoking will mask the alarm pheromone secreted by the guard bees waiting at the entrance, so the rest of the colony is not prone to sting. The smoke also drives the bees to the comb where they engorge on honey, presumably because they believe their tree is burning down, and they'll need to swarm and find a new home. Of course, you only blow a few puffs of smoke in the entrance, so they stop believing their tree is being consumed by fire. With the bees full of honey, they will be far less likely to sting.
NOTE: If you fail to smoke the hive before opening it, the bees will not only be aggressive and will likely sting, but they may continue their aggressive behavior into the future. Always smoke a hive before opening it.
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Feeding and Watering
Opening and Feeding the Hive
Preparing to Visit the Apiary